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- The brand new dz2 and you may dx2-y2 orbitals lack as the lead contact since the ligands form of fit previous or fall because of the these types of orbitals, therefore reducing the electron-electron repulsion as well as the opportunity of one’s orbital.
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In the equipment of your shorter Planck constant ħ, all of the particles you to move in 3 size have possibly integer twist and follow Bose-Einstein analytics or 50 percent of-integer spin and obey Fermi-Dirac statistics. Because the bromo ligand try a weak career ligand , so it molecule is highest spin. The newest breaking away from tetrahedral buildings is actually in person opposite that the newest splitting of one’s octahedral buildings. Bear in mind one to inside the octahedral buildings, the newest dz2 and you can dx2-y2 orbitals have highest times compared to the dxz, dxy, and you will dyz orbitals. Inside tetrahedral buildings, the exact opposite occurs because the dxz, dxy, and you will dyz orbitals features higher times compared to the dz2 and you may dx2-y2 orbitals.
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